Hot Perspective: Shedding light on the oxygen-evolving-complex

Can we mimic the Photosystem II machinery for light-driven oxidation of water to molecular oxygen?

Can we mimic the Photosystem II machinery for light-driven oxidation of water to molecular oxygen?

In this Dalton Transactions Perspective,Philipp Kurz and colleagues discuss manganese-containing compounds that have been studied as potential analogues of the oxygen-evolving-complex in Photosystem II.  They highlight how the desire to produce solar fuels is inspiring research into artificial photosynthesis.

Read more for free until 29th November at:

Water oxidation catalysed by manganese compounds: from complexes to ‘biomimetic rocks'
Mathias Wiechen,Hans-Martin Berends and Philipp Kurz
Dalton Trans.,2012,Advance Article
DOI:10.1039/C1DT11537E,Perspective

You might also find theseDalton Trans.articles on biomimetic water-oxidation catalysis interesting…

Nano-size amorphous calcium–manganese oxide as an efficient and biomimetic water oxidizing catalyst for artificial photosynthesis: back to manganese
Mohammad Mahdi Najafpour,Sara Nayeri and Babak Pashaei
Dalton Trans.,2011,40,9374-9378
DOI:10.1039/C1DT11048A

High turnover catalysis of water oxidation by Mn(II) complexes of monoanionic pentadentate ligands
Rune Kirk Seidler-Egdal,Anne Nielsen,Andrew D.Bond,Morten J.Bjerrum and Christine J.McKenzie
Dalton Trans.,2011,40,3849-3858
DOI:10.1039/C0DT01340D

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