Despite the wordy and jargon laden title this paper by Wang et al presents interesting work on a highly novel class of luminescent material.
通常理解的是,当发色团聚集它们的发射被淬灭,事件知道的聚集引起的淬灭(ACQ)。与此ACQ出现的主要问题是,它限制了在应用,例如生物成像和传感器在亮度为键,使用这些发光分子。
针对这一许多研究小组都集中在开发是ACG的和在发色团的聚集,实际上促进发光的完全相反的材料。这种现象被称为聚合诱导的发射(AIE)。
This paper presents work about a novel type of AIE material that overcomes the shortfalls of ACG and some other previous AIE luminogens. A red-emissive barbituic acid-functionalized TPE derivative (TPE-HPh-Bar) was designed and synthesized, the resulting material exhibits both AIE and also twisted intramolecular charge transfer (TICT). By altering the method of synthesis the TPE-HPh-Bar is capable of self-assembling into nanospheres, -rods and -tubes. All of these exciting characteristics indicate that this novel material could be used in a wide range of applications from biological imaging to optoelectronic nano-devices in the future.
扭曲分子内电荷转移,聚集诱导发射,超分子自组装和barbituic酸官能化的四苯乙烯的光波导
Erjing王,张学友W. Y.林,李荣融胡,张闯,永晟赵奔唐忠
J.母校。化学。C, 2014, 2, 1801-1807. C3TC32161D
H. L. Parker is a guest web writer for the Journal of Materials Chemistry blog. She currently works at the Green Chemistry Centre of Excellence, the University of York.
为了跟上最新的所有最新的研究成果,登录到我们的RSS feed要么Table of contents alert。