网址：//www.xcmww.com/cc 清华大学，2019年1月31日13:56:52+0000 en美国 每小时 1个 https://wordpress.org/？V=4.9.9 //www.xcmww.com/cc/2019/01/31/saving-organic-electors-in-锂离子电池/ //www.xcmww.com/cc/2019/01/31/在锂离子电池中保存有机电极/响应 清华大学，2019年1月31日13:56:52+0000 刘天宇 热门文章 材料 电池 阴极 循环稳定性 //www.xcmww.com/cc/？P＝9521 具有共轭电子结构的有机化合物由于其高容量和环保性，正逐渐成为有前途的锂离子电池阴极。为了使这些阴极切实可行，有机电极通常与金属离子结合以提高其能量密度。金属离子的加入，然而，通常会危害电极的结构完整性和[…] <p>具有共轭电子结构的有机化合物由于其高容量和环保性，正逐渐成为有前途的锂离子电池阴极。为了使这些阴极切实可行，有机电极通常与金属离子结合以提高其能量密度。金属离子的加入，然而，通常会危害电极的结构完整性，缩短电池寿命。<p>最近，三组中国研究人员证明，提高电解质浓度可以有效延长金属有机阴极的寿命。研究人员研究了四氟化亚铜（Cutcnq）。a cu<sup>2+<sup>—containing organic li-ion battery negative，a cu<sup>2+<sup>—containing organic li-ion battery negative，与1 M电解质相比，7 M LiClO<Sub>4<Sub>电解质显著改善了循环稳定性。这项工作最近发表在《化学操作手册》（Chemcomm）中，在1 M LiClO<Sub>4的典型稀释电解质中显示出不令人满意的稳定性。其第一次循环充电容量达到~180 mAh/g，但在第一次放电过程后，它明显下降到23 mAh/g（图1a）。同时，电解液从透明变为黄色（图1b）。由于TCNQ的溶解。这些观察清楚地显示了稀释电解质中Cutcnq的快速分解。<p><div id=“attachment_9522”style=“width:661px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2019/01/1.jpg”><img class=“wp-image-9522”src=“//www.xcmww.com/cc/files/2019/01/1.jpg”alt=“”width=“651”height=“284”srcset=“//www.xcmww.com/cc/files/2019/01/1.jpg 1146w，//www.xcmww.com/cc/files/2019/01/1-300x131.jpg 300w，网址：//www.xcmww.com/cc/files/2019/01/1-768x335.jpg 768W，//www.xcmww.com/cc/files/2019/01/1-1024x447.jpg 1024w“尺寸=”（最大宽度：651px）100vw，651px“/><a><p class=“wp caption text”><em><strong>Figure 1</strong>。（a）含有碳酸乙烯酯（EC）的液体电解质中CuTCNQ的第一个循环充放电曲线，碳酸丙烯酯（PC）和1 M LiClO4（1 M LiClO4 EC/PC）。（b）显示第一次充放电循环前后电解质颜色的照片。<em><p><div><p>Cutcnq was found to be more stable in electronates with concentrations higher than 1 m.当LiClO<Sub>4<Sub>浓度增加到3 m时，5米和7米，连续50次充放电循环后，Cutcnq的比容量为~25 mAh/g，约70 mAh/g，和110毫安/克，分别（图2a）。在相同的循环数（<10 mAh/g）后，所有这些容量均高于1 m LiClO<Sub>4<Sub>Cutcnq的容量。此外，电解质几乎没有变色，建议溶解少量TCNQ（图2b）。<p><p>The highed stability of cutcnq correlates to the formation of li<sup>+<sup>-clo<sub>4<sub><sup>-<sup>ion pairs in concentrated electronologies（图2c）。随着LiClO<Sub>4<Sub>Concentration的增加，li<sup>+<sup>and clo<sub>4<sub><sup>-<sup>trend to form ion ion pairs that coordinate with solution molements.溶剂配位减少了可溶解TCNQ的游离溶剂分子的数量，因此，尽量减少tcnq的溶解。<p><div id=“attachment_9523”style=“width:684px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2019/01/2.jpg”><img class=“wp-image-9523”src=“//www.xcmww.com/cc/files/2019/01/2.jpg”alt=“”width=“674”height=“282”srcsset=“//www.xcmww.com/cc/files/2019/01/2.jpg 1308w，//www.xcmww.com/cc/files/2019/01/2-300x126.jpg 300w，网址：//www.xcmww.com/cc/files/2019/01/2-768x322.jpg 768W，//www.xcmww.com/cc/files/2019/01/2-1024x429.jpg 1024w“尺寸=”（最大宽度：674px）100vw，674px“/><a><p class=“wp caption text”><em><strong>Figure 2<strong>。（a）不同浓度LiClO4电解质对CuTCNQ循环稳定性的影响。（b）显示不同LiClO4浓度下50次充放电循环前后电解质颜色的照片。（c）在超浓缩电解质（例如7 m）.<em><p><div><p>This work provides a facile approach to relative the capacity failding of cutcnq.该策略可以扩展到稳定锂离子电池中的其他金属有机阴极。<p><p><strong><u>to find out more please read:<u><strong><p><strong><a href=“https://pubs.rsc.org/en/content/articlelanding/2019/cc/c8cc09307e！DivAbstract“>锂有机电池用高浓度电解质实现的可持续循环春芳，王张刘庆菊和黄云辉公社。.<em>.<strong>，2019年，55岁，608-611</p><p><strong><u>about the blogger:<u><strong><p><img class=“AlignLeft wp-image-6451”src=“//www.xcmww.com/sc/files/2018/12/tianyu_2018-223x300.jpg”alt=“”width=“87”height=“117”/>tianyu liu obtained his ph.d.（2017）加州大学新利手机客户端化学专业，美国的圣克鲁斯。他热衷于科学传播，向公众和具有不同研究专长的科学家介绍尖端研究。他是化学的博客作家。common.<em>和<em>chem.科学>杂志。有关他的更多信息，请访问http://liutianyuresearch.weebly.com/“>http://liutianyuresearch.weebly.com/<a><p><div class=“lightsocial\u container”><a class=“lightsocial\u a”href=“http://digg.com/submit”？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2019%2f01%2f31%2在锂离子电池中保存有机电极%2f&title=saving+organic+electors+in+limithium-ion+batteries“><img class=“light social\u img”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/digg.png”alt=“digg this”title=“digg”/><a class=“light social\u 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Shoyama先生，Matthias Stolteb和Frank W_rthner Chem。公社，2018，54岁，13763-13772 doi:10.1039/c8cc0764oe，重点介绍单原子fe–n4催化位点模拟双功能抗氧化酶用于[…] <p><strong>在1月18日星期五之前，以下所有裁判员推荐的文章都是免费的。<strong><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc07640e“><strong>萘和聚乙烯二亚胺-有机电子产品富勒烯的更好替代品？<br/>Agnieszka Nowak kr_l，Kazutaka Shoyama先生，Matthias Stolteb and Frank W_rthner<br/><em>Chem.社区->2018，<strong>54<strong>，13763-13772<br/><strong>doi:<strong>10.1039/c8cc0764oe，highlight</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc07640e“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageinfo.imagetype=ga&imageinfo.imageidentifier.manuscriptid=c8cc07640e“alt=”萘和聚乙烯二胺；有机电子中富勒烯的替代品。“width=“374”height=“189”/><p><p>><p>UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuudoi=10.1039/c8cc08116f“><strong>a single atom fe–n4 catalystic site mixiking biffutional antioxide measures for oxiday stress cytoprotection.<strong><a><br/>wenjie ma，毛俊杰杨晓蒂，从盘，陈文星，王明，平宇，毛兰群和李亚东<br/><em>chem.社区->2019年，advance article<br/><strong>doi:<strong>10.1039/c8cc0816f，通信</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc08116f“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C8CC08116F" alt="Catalytic site mimicking bifunctional antioxidative enzymes" width="222" height="191" /></a></p><p style="text-align: center">___________________________________________________________</p><p><a href="http://xlink.rsc.org/?doi=10.1039/c8cc07681b“><strong>si（bzimpy）2–a hexacoordinate silicon pincer complex for electrone transport and electronic lightnes.<strong><a><br/>Margaret Kocherga，Jose Castaneda米迦勒G沃尔特雍张尼玛阿拉萨利赫，王乐，丹尼尔S。琼斯，Jon Merkert伯纳黛特·多诺万·默克特，闫增丽Tino Hofmann和Thomas A.Schmedake<br/><em>Chem.社区->2018，<strong>54<strong>，14073-14076<br/><strong>doi:<strong>10.1039/c8cc07681b，通信</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc07681b“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageinfo.imagetype=ga&imageinfo.imageidentifier.manuscriptid=c8cc07681b“alt=”六坐标硅钳复合物；电子传输和电致发光的应用。“width=“378”height=“146”/><p><p style=“text style=“text-Align：中心”>UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUuxLink.rsc.org/？DOI＝10.1039／C8cc08501C＞<强>自催化酶反应在溶胶-凝胶转变中保持均一性< <强> < /> > BR> Santanu Panjaa和Dave J.亚当斯化学社区->2019年，advance article<br/><strong>doi:<strong>10.1039/c8cc08501c，通信</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc08501c“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageinfo.imagetype=ga&imageinfo.imageidentifier.manuscriptid=c8cc08501c“alt=”溶胶-凝胶转变中的自催化酶反应；保持同质性。“width=“257”height=“189”/><p><p style=“text style=“text-align：中心”>>UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUp><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc08134d“><strong>去铁氧胺：镓多糖胶束增加外膜渗透性，增强抗生素活性，对抗<em>铜绿假单胞菌<em><strong><a><br/>max purro，晶桥，Zhi Liu摩根·阿什克拉夫特和梅·P。熊<br/><em>chem.社区->2018，<strong>54<strong>，13929-13932<br/><strong>doi:<strong>10.1039/c8cc08134d，通信</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc08134d“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C8CC08134D" alt="Micelles increase outer membrane permeability and provide antibiotic activity against Pseudomonas aeruginosa." width="332" height="189" /></a></p><p style="text-align: center">___________________________________________________________</p><p><a href="http://xlink.rsc.orG/？doi=10.1039/c8cc08456d“><strong>unbalanced mof on mof growth for the production of a opsided core–shell of mil-88b@mil-88a with mismatched cell parameters.<strong><a><br/>dooyng kim，李智贤，sojin oh and moonhyun oh<br/><em>chem.社区->2019年，advance article<br/><strong>doi:<strong>10.1039/c8cc08456d，通信</p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc08456d“><img class=“AlignCenter”src=“https://pubs.rsc.org/en/image/get？”imageinfo.imagetype=ga&imageinfo.imageidentifier.manoscriptid=c8cc08456d“alt=”mof on mof growth；mil-88b@mil-88a.“width=”378“height=”157“/><a><p><p>.<p><div class=”lightsocial_container“><a class=”lightsocial_a“href=”http://digg.com/submit？url=http%3a%2f%2f%2fbloblog.rsc.org%2fccc%22018%2f2018%2f12%22018%2f18%2fhot-chemchom-chemchom-文章-for-11-11-2%2f&title=hot+chemcom+文章+for+11“><img class=“Light社交”img”src=“http://blog.rsc.org/cc/wwp-内容/插件/轻-社会/digg.png”alt=“digg this”title=“digg本”/>，/>，/>，&a>160；<a class=“Light社会生活”a 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//www.xcmww.com/cc/2018/11/28/cram-lehn-pedersen-prize-2019-call-for-nominations/回复 结婚，2018年11月28日09:07:39+0000 Chris Harding开发编辑 奖品 //www.xcmww.com/cc/？P＝9496 国际大环和超分子化学研讨会国际委员会很高兴邀请对年轻超分子化学家Cram-Lehn-Pedersen奖的提名。新利手机客户端Cram Lehn Pedersen奖，以纪念1987年诺贝尔化学奖获得者命名，新利手机客户端认识到超分子化学中重要的原创和独立的工作。新利手机客户端前几位获奖者[…] <p><a href=“//www.xcmww.com/cc/files/2018/11/clp.png”><img class=“Alignnone wp-image-9497 size full”src=“//www.xcmww.com/cc/files/2018/11/clp.png”alt=“”width=“4876”height=“1634”srcset=“//www.xcmww.com/cc/files/2018/11/clp.png 4876w，//www.xcmww.com/cc/files/2018/11/clp-300x101.png 300w，//www.xcmww.com/cc/files/2018/11/clp-768x257.png 768w，//www.xcmww.com/cc/files/2018/11/clp-1024x343.png 1024w“尺寸=”（最大宽度：4876px）100vw，4876px“/>.<a><p><p>The international committee of the international conference on the macrocycle and supra molecul新利手机客户端ar chemistry is pleasure to invite nominations for the cram-lehn-pedersen prize for young supra molecular chemists.<p><p>the cram-lehn-pedersen prize，以纪念<a href=“http://www.nobel prize.org/nobel_prices/chemistry/laure新利手机客户端ates/1987/”>1987年诺贝尔化学奖获得者命名认识到超分子化学中重要的原创和独立工作。<p>以前的获奖者包括<a href=“//www.xcmww.com/cc/2018/03新利手机客户端/06/恭喜-to-the-2018-cram-lehn-pederson-prize-winner-rafal-klajn/”>rafal klajn<a>，<a href=“//www.xcmww.com/cc/2017/06/08/恭喜-to-the-2017-cram-lehn-pedersen-prize-win纳汤姆·德格里夫/“>汤姆·F.a.De Greef</a>，；<a href=“//www.xcmww.com/cc/2016/05/2016/05/31/Ivan aprahamian Wins Cram Lehn Pedersen奖/“>Ivan aprahoamian>，；<a href=“http://blog.rsc.org/cc/2015/2015/06/23/Feihe-huang-wins-crm-lehn-pedersen-pedersen-2015/“>Fehehuhua>，，；<a href=“http://blohttp://blog.rsc.org/2016/2016/2016/05/2016/05/31/31/31/伊凡apra哈帕拉哈阿米an-Ivan-apraham-apraham-Su-pedersen-prize-2014/“>oren schermann<a>，<a href=“//www.xcmww.com/cc/2013/03/28/tomoki-ogoshi-wins-cram-lehn-pedersen-prize-2013/”>tomoki ogoshi</a>，<a href=“//www.xcmww.com/cc/2011/08/30/cram-lehn-pedersen prize-%e2%80%93-2012-winner-announced/”>jonathan nitschke</a>，以及<a href=“//www.xcmww.com/cc/2011/01/26/cram lehn pedersen prize winner announced/”>Amar Flood<a><p>The those who are within 10 years of receiving their phd on 31 december 2018 are qualified for the 2019 Award.获胜者将获得2000英镑的奖金，并免费注册LECCE中的ISMSC会议。意大利。除了在ISMSC做讲座外，会议结束后，将与《化学通讯》编辑协商，组织一次简短的讲座参观。该奖项的发起人。<p><strong>提名详情：<strong><p><p>Please send your cv，出版物清单（分为博士和博士后的出版物和独立工作的出版物）如有需要，支持函，或者这些材料给你想提名给教授的人。Roger Harrison（ISMSC秘书），地址：roger_harrison@byu.edu by<strong>31<sup>st<sup>2018年12月</strong><p><p><p><div class=“lightsocial_container”><a class=“lightsocial_a”href=“http://digg.com/submit”？url=http%3a%2f%2fblowww.xcmww.com%2fccc%22018%22018%2f11%2f28%2ffram-lehn-pedersen-奖-2019-2019-Call-for-提名%2f&title=crm+lehn+pedersen+奖+2019+%e2%80%93+Call+for+提名“><img class=“Light社会\img”src=“http://blog.rsc.org/cc/wwp-conte/plugins/lig-社会/digg.png.png”alt=“digg本”title=“digg=“digg本”/>，/>>>a>160；<160；；；<a>><160g a class=“light 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class=“lightsocial_a”href=“http://www.technorati.com/faves”？add=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f28%2fcram-lehn-pedersen-prize-2019-call-for-nominations%2f“><img class=“light social\u img”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/technorati.png”alt=“bookmark this on technorati”title=“bookmark this on technorati”/>=<a class=“light social\u a”href=“http://twitter.com/ho我？status=reading+http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f28%2fcram-lehn-pedersen-prize-2019-call-for-nominations%2f“><img class=“light social_img”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/twitter.png”alt=“post on twitter”title=“post on twitter”/>=<a class=“light social_a”href=“http://www.google.com/buzz/post”？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f28%2fcram-lehn-pedersen-prize-2019-call-for-nominations%2f“><img class=“light social_img”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/google_buzz.png”alt=“google buzz（aka）。google reader）“title=”google buzz（aka.google reader）“/>.<a>.<div> //www.xcmww.com/cc/2018/11/28/cram-lehn-pedersen-prize-2019-call-for-nominations/feed/ 0 //www.xcmww.com/cc/2018/11/20/scaling-the-size-of-hydrogen-evolution-catalysts-by-carbon-coating/ //www.xcmww.com/cc/2018/11/20/通过碳涂层缩小氢进化催化剂的尺寸/回应 星期二，2018年11月20日15:24:31+0000 刘天宇 热门文章 无机物 催化剂 氢演化 纳米颗粒 钌 //www.xcmww.com/cc/？P=9459 氢气是一种零排放的能源，有望取代日益减少的化石燃料。电解水是获得氢气的一种可持续方法，但这种非自发的过程需要电力来进行。因此，利用析氢反应（HER）催化剂降低电解能耗或降低电解过电位。研究人员正在研究超细材料。 <p>氢气是一种零排放的能源，有望取代日益减少的化石燃料。电解水是获得氢气的一种可持续方法，但这种非自发的过程需要电力来进行。因此，氢进化反应（HER）催化剂用于降低电解的能源成本或过电位。<p>由于其高催化活性，研究人员正在研究超细纳米颗粒作为她的催化剂。例如，据报道，Ru纳米粒子的催化活性比散装Ru催化剂高100-200%。不幸的是，制备分散良好的纳米颗粒具有挑战性，因为纳米颗粒容易聚集在一起。<p><p>Recently in<em>Chemcomm<em>，傅强楚秦勇和常州大学的同事们，中国应对了这一挑战。他们使用一种Ru基配位络合物和三聚氰酸作为反应物，合成了~2纳米Ru纳米粒子均匀分散在石墨烯片上的高性能HER催化剂。在合成的热退火过程中，配合物的配体和三聚氰酸都分解为氮掺杂的碳壳，覆盖形成的Ru纳米粒子。这些外壳充当防止颗粒聚集的间隔物（图1）。<p><div id=“attachment_”style=“width:445px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2018/11/1-1.jpg”><img class=“wp-image-9465”src=“//www.xcmww.com/cc/files/2018/11/1-1.jpg”alt=“”width=“435”height=“214”srcset=“//www.xcmww.com/cc/files/2018/11/1-1.jpg 378w，网址：//www.xcmww.com/cc/files/2018/11/1-1-300x148.jpg 300w“尺寸=”（最大宽度：435px）100vw，435px“/><a><p class=“wp caption text”><em><strong>Figure 1</strong>。石墨烯片上碳包覆的Ru超细纳米颗粒的合成实例。Tris（2,2′-联吡啶）二氯化钌是Ru纳米粒子的前体。<em><p><div><p>in both the酸性和碱性电解质，2纳米Ru粒子（RUNC-2）显示的过电位较低，电流密度高于不含碳涂层的5纳米Ru粒子（图2）（RUNC-5）。值得注意的是，2纳米颗粒在酸性电解质中表现出与基准铂催化剂相当的性能（图2a中的红色和黑色曲线）。<p><div id=“attachment_”style=“width:1744px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2018/11/2-1.jpg”><img class=“wp-image-9468 size full”src=“//www.xcmww.com/cc/files/2018/11/2-1.jpg“alt=”width=“1734”height=“687”srcset=“//www.xcmww.com/cc/files/2018/11/2-1.jpg 1734w，//www.xcmww.com/cc/files/2018/11/2-1-300x119.jpg 300w，//www.xcmww.com/cc/files/2018/11/2-1-768x304.jpg 768W，//www.xcmww.com/cc/files/2018/11/2-1-1024x406.jpg 1024w“尺寸=”（最大宽度：1734px）100vw，1734px“/><a><p class=“wp caption text”><em><strong>Figure 2</strong>。~3纳米铂纳米粒子（ptnc）的线性扫描伏安图，2纳米Ru纳米粒子（runc-2）和5纳米Ru纳米粒子（runc-5）in（a）0.5 m h<sub>2<sub>so<sub>4<sub>and（b）1 m koh水溶液。<em>><p>The concept of the<em>in-situal.<em>Generation of protective coatings could inspire the synthesis of other ultra small nandoms to potentially push the her catalystical performance to new高度。<p><p><p><p><strong><u>to find out more please read:<u><strong><p><strong><a href=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc08276f！DivAbstract“>酸性和碱性介质中的氢演化反应具有极高活性的超细钌纳米晶体傅强楚杨柳，金刚，陶永信，李永新和秦永新公社。.<em>.<strong>，2018，doi:10.1039/c8cc08276f<p><p><p><strong><u>about the blogger:<u><strong><p><img class=“AlignLeft”src=“http://liutianyuresearch.weebly.com/uploads/9/1/0/7/91072250/liu-tianyu-photo.jpg？187“alt=”width=“112”height=“134”/>刘天宇获得博士学位。（2017）加州大学新利手机客户端化学专业，美国的圣克鲁斯。他热衷于科学传播，向公众和具有不同研究专长的科学家介绍尖端研究。他是化学的博客作家。common.<em>和<em>chem.科学>杂志。有关他的更多信息，请访问http://liutianyuresearch.weebly.com/“>http://liutianyuresearch.weebly.com/<a><p><div 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//www.xcmww.com/cc/2018/11/20/shrinking-the-size-of-hydrogen-evolution-catalysts-by-carbon-coating/feed/ 0 //www.xcmww.com/cc/2018/11/07/hot-chemcomm-articles-for-10月4日/ //www.xcmww.com/cc/2018/11/07/hot-chemcomm-articles-for-10月4日/回复 结婚，2018年11月7日13:38:59+0000 丽贝卡威瑟斯 未分类 //www.xcmww.com/cc/？P=9449 在2018年12月7日之前，以下所有裁判员推荐的条款都是免费的。由dnp-nmr-wing-ying-chow检测到的必要但稀疏的胶原羟基赖氨酸翻译后修饰，李睿，伊娃·戈德伯格，大卫G。瑞德拉凯什·拉詹，Jonathan Clark哈特穆特·奥什基纳特，梅林达J。度秘，罗伯特·海沃德和凯瑟琳·M。Shanahan化学公司公社，2018，5412570-12573 doi:…] <p><strong>在2018年12月7日之前，以下所有裁判员推荐的文章都是免费的。<strong><p><a href=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc04960b！DivAbstract“><strong>Essential but sparse collagen hydroxyysyl post-translational modifications detected by dnp nmr.<strong><a><br/>Wing Ying chow，李睿，伊娃·戈德伯格，大卫G。瑞德拉凯什·拉詹，Jonathan Clark哈特穆特·奥什基纳特，梅林达J。度秘，罗伯特·海沃德和凯瑟琳·M。Shanahan<br/><em>Chem.社区->2018，5412570-12573<br/><strong>doi:<strong>10.1039/c8cc04960b，communication<p><a href=“//www.xcmww.com/cc/files/2018/11/1.jpg”><img class=“AlignCenter size full wp-image-9450”src=“//www.xcmww.com/cc/files/2018/11/1.jpg”alt=“”width=“387”height=“194”srcset=“//www.xcmww.com/cc/files/2018/11/1.jpg 387w，//www.xcmww.com/cc/files/2018/11/1-300x150.jpg 300w“尺寸=”（最大宽度：387px）100vw，387px”/>-<P><P style=“text-Align：中心”>>UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06399k！De＞强〉Ni泡沫塑料快速原位合成Co＜强＞3＞/强＞＞强＞O4纳米片阵列，用于空气氧等离子体刻蚀CO（OH）2的有效析氧< <强> < /A> < BR> >温岭谷，胡柳勇，萧青竹常熟上，王静丽和王二康<br/><em>chem.社区->2018，advance article<br/><strong>doi:<strong>10.1039/c8cc06399k，communication<p><a href=“//www.xcmww.com/cc/files/2018/11/2.jpg”><img class=“AlignCenter size full wp-image-9451”src=“//www.xcmww.com/cc/files/2018/11/2.jpg”alt=“”width=“397”height=“106”srcset=“//www.xcmww.com/cc/files/2018/11/2.jpg 397w，//www.xcmww.com/cc/files/2018/11/2-300x80.jpg 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<一个MOC，我这周学的，是一个金属有机笼子。我和妈妈很熟，MOF和MOB，但是主运行中心是一个新的。MOM（金属有机材料）是由有机配体连接的金属节点构成的协调驱动组件。MOM包括MOF（金属有机框架）和MOC（金属有机笼）。MOF是一个扩展的网络，具有潜在的内部孔隙，MOC是一个离散的金属配体簇。这就是我愿意去的兔子洞这个术语的最下面部分。如果你能跟上，你会发现我忘了一个！一群研究生在公共研讨会上争夺免费咖啡。<p>Dong和山东师范大学的同事们设计并准备了一种由铜（II）节点和三脚架配体构成的MOM催化剂，该催化剂由苯基轮和二酮组成。在氯仿中，这两种成分排列成含有两个三脚架配体和三个铜离子的分立MOC组件。群集中的铜离子均以准方形平面排列与两个二酮部分（类似乙酰丙酮）协调。<p><div style=“width:317px”class=“wp caption aligncenter”><img src=“https://pubs.rsc.org/services/images/rsc pubs.eplatform.service.freecontent.imageservice.svc/imageservice/articleimage/2018/cc/c8cc07208f/c8cc7208f-s1_hi-res.gif“alt=”与二酮配位部分功能化的三脚架配体的合成。“width=“307”height=“148”/><p class=“wp caption text”>synthesis of the tribal配体functionalized with diketone coordinating moites.<p>><p>an interest property of the material is that it can switch between the moc form，溶于卤化溶剂，以及一种不溶性MOF，在加入1，4-二恶烷后聚集。1，4-二恶烷既是一种抗溶剂又是一种配体；铜和1,4-二恶烷之间的配位将离散的MOC笼彼此结合，将它们安排到扩展的MOF结构中。这种行为可以用来制备一种实用的催化剂，这种催化剂结合了均相催化和多相催化的优点，也就是说，均相催化剂通常效率更高，有选择性且容易学习，但是多相催化更容易回收和循环。有什么比在反应条件下使用均质催化剂更好的方法来解决这个问题？但当涉及到产品分离时，是异构的吗？<p><div style=“width:387px”class=“wp caption aligncenter”><img src=“https://pubs.rsc.org/services/images/rsc pubs.eplatform.service.freecontent.imageservice.svc/imageservice/articleimage/2018/cc/c8cc7208f/c8cc7208f-f1_hi-res.gif”alt=“Reversible metal organic cage moc（top left）-mof（top right）metal organic framework transition mediated by the添加1,4-二恶烷。显示1,4-二恶烷之间的配位键（下图）。“width=”377“height=”236“/><p class=”wp caption text“>通过添加1,4-二恶烷介导的可逆MOC（左上）-MOF（右上）转变。所示1,4-二恶烷之间的配位键（底部图像）。<p>><div><p>The authors used the a<sup>3<sup>coupling reaction to example this concept in a catalystical reaction.A<sup>3<sup>反应是一种催化过渡金属，醛之间的多组分耦合反应，炔烃和胺。产品为丙炔胺，合成氮杂环化合物的实用合成中间体。a<sup>3<sup>反应已被广泛研究，并可受到各种过渡金属催化剂的影响。其多功能性使其成为催化反应模型的流行选择，以证明催化设计中的创新理念——正如作者在这里所做的。<p>Coordination Driven Assemblies have a unique potential for the synthesis of differentially solving materials，作者用于新型催化设计。这种特殊的金属配体组合能否应用于其他铜催化反应，还有待观察。尽管如此，该原理还是提供了一种创新的方法，扩大了各种方法的范围，努力弥合同质催化和异类催化之间的差距。<p><p><span style=“text-decoration:underline”><strong>to find out more please read:<strong><span><p><p><a href=“http://xlink.rsc.org/？doi=10.1039/c8cc07208f“>cu<sub>3<sub>l<sub>2<sub>metal organic cames for a<sup>3<sup>-coupling reactions:Reversible coordination interaction trigged sequency catalysis and heterogeneous recovery<a>><p>gong jun chen，陈超群，薛天丽，许朝马、于斌东。<br/><em>chem.公社。<em>，2018，<strong>54<strong>，11550-11553<br/><strong>doi<strong>：10.1039/C8c7208f<p><p><p><span style=“文本装饰：下划线“><stron强><img class=“wp-图像-8928 Align左”src http://博客.rsc.org/cc/文件/2018/01/zoehheane_pic_cropped-258x300.jpg“alt=宽度=“126”高度=“147”srcsset=“http://博客.rsc.org/cc/文件/2018/2018/01/01/zoehheanee_pic-Cropped-258x300.258x300.jpg 258x300.258x300.258w-258x300.JP258x300.JP2588如果你不愿意的话，//www.xcmww.com/cc/files/2018/01/zoehearne-pic-cropped-768x894.JPG 768W，//www.xcmww.com/cc/files/2018/01/zoehearne-pic-cropped.jpg 778w“size=”（最大宽度：126px）100vw，126px“/>about the author</strong><span><p>zo_hearne is a phd candidate in chemist新利手机客户端ry at mcgill university in montr_al，加拿大在李超教授的监督下。她来自堪培拉，澳大利亚，在那里她完成了她的本科学位。她目前的研究重点是过渡金属催化，以实现新的转变，在实验室之外，她是一名热情的化学导师和科学传播者。<p><div class=“li新利手机客户端ghtsocial_con新利手机客户端tainer”><a class=“lightsocial_a”href=“http://digg.com/submit”？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f06%2fcopper-a3-coupling-using-a-switchable-simpous-异构-catalyst%2f&title=copper+a3+coupling+using+a+switchable+simpous%2fe异种+catalyst“><img class=“light social\uimg”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/digg.png”alt=“digg this”title=“digg this”/>_<a 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class=“lightsocial_a”href=“http://www.technorati.com/faves”？add=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f06%2fcopper-a3-coupling-using-a-switchable-simonsious-异构-catalyst%2f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/technorati.png“alt=”bookmark this on technorati“title=”bookmark this on technorati“/><a>”=“http://twitter.com/home？status=reading+http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f06%2fcopper-a3-coupling-using-a-switchable-sequency-hyperious-catalyst%2f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/twitter.png“alt=”post on twitter“title=”post on twitter“/><a class=”light social_a“href=”http://www.google.com/buzz/post？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f11%2f06%2fcopper-a3-coupling-using-a-switchable-simpous-异构-catalyst%2f“><img class=“light social”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/google_buzz.png”alt=“google buzz（aka）。google reader）“title=”google buzz（aka.google reader）“/>.<a>.<div> //www.xcmww.com/cc/2018/11/06/copper-a3-coupling-using-a-switchable-sequency-异质催化剂/feed/ 0 //www.xcmww.com/cc/2018/10/22/the-birth-of-a-半导体-金属-有机-框架-硫-协调/ //www.xcmww.com/cc/2018/10/22/the-birth-of-a-semiconducting-metal-organic-framework-by-sulfur-coordination/回复 周一，2018年10月22日10:08:47+0000 刘天宇 热门文章 无机物 材料 财政部 硫黄 TETRA协调 //www.xcmww.com/cc/？P=9440 金属有机骨架（MOF）是由金属离子或与有机配体配位的簇组成的结晶纳米材料。由于其构建模块的多功能性，MOF具有多种功能，可作为气体分离器。传感器，催化剂，电极材料等现在，吴先生和苏州的同事们进一步丰富了MOF的结构多样性。 <p>金属有机骨架（MOF）是由金属离子或与有机配体配位的簇组成的结晶纳米材料。由于其构建模块的多功能性，MOF具有多种功能，可作为气体分离器。传感器，催化剂，电极材料现在，吴先生和苏州大学的同事们进一步丰富了财政部的结构多样性。中国。明确地，研究人员用四配位硫单元合成了一种半导体MOF。这一突破最近发表在《化学命令》（Chemcomm）中，合成半导体MOF（MCOF-89）的唯一性是其方形平面四配位金属硫结构，首次在财政部观察到。据信，将硫原子放在MOF的金属节点旁边非常困难，由于金属硫键与传统的金属羧酸键在键能上存在较大差异。因此，加入硫原子可能会破坏MOF的结构稳定性。<p>作者通过设计图1所示的四配位环境来解决这一挑战。四锰硫键有效地增强了不稳定S配位。MCOF-89是通过与锰的溶剂热反应合成的（CH<Sub>3<Sub>COO）<Sub>2<Sub>和硫脲作为锰和硫源，分别。<p><div id=“attachment_”style=“width:563px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2018/10/1-1.jpg”><img class=“wp-image-9441”src=“//www.xcmww.com/cc/files/2018/10/1-1.jpg”alt=“”width=“553”height=“292”srcsset=“//www.xcmww.com/cc/files/2018/10/1-1.jpg 1216w，//www.xcmww.com/cc/files/2018/10/1-1-300x159.jpg 300w，//www.xcmww.com/cc/files/2018/10/1-1-768x406.jpg 768W，//www.xcmww.com/cc/files/2018/10/1-1-1024x541.jpg 1024w“尺寸=”（最大宽度：553px）100vw，553px“/><a><p class=“wp caption text”><em><strong>Figure 1</strong>。MCOF-89的结构。左边的插图是一个三维格子结构（红色，绿色和黄色的球代表氧气，锰和硫）右边的结构显示了mn-s方形平面四配位配置（m=锰）。<em><p><p>The synthed s-incorporated m of is a semiconductor with a bandgap of 2.82 ev.此外，该MOF具有光活性，能够在光照射下产生约1.9μA/cm<sup>2<sup>它还可以激发其他合成协议，以获得各种金属硫族化合物，其中含有具有意想不到的特性的MOF。<p><p><p><strong><u>to find out more please read:<u><strong><p><strong><a href=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06997b！DivAbstract“>A Semiconducting metal chalcogenide–organic framework with square planar tetra coordinated sulfur.<A><strong><P>Huajun Yang，Min LuoZhou Wu王玮薛朝庄、吴涛公社。.<em>.<strong>，2018，54岁，11272-11275</p><p><p><p><strong><u>about the blogger:<u><strong><p><img class=“AlignLeft”src=“http://liutianyuresearch.weebly.com/uploads/9/1/0/7/91072250/liu-tianyu-photo.jpg？187“alt=”width=“112”height=“134”/>刘天宇获得博士学位。（2017）加州大学新利手机客户端化学专业，美国的圣克鲁斯。他热衷于科学传播，向公众和具有不同研究专长的科学家介绍尖端研究。他是化学的博客作家。common.<em>和<em>chem.科学>杂志。有关他的更多信息，请访问http://liutianyuresearch.weebly.com/“>http://liutianyuresearch.weebly.com/<a><p><div class=“lightsocial\u container”><a class=“lightsocial\u a”href=“http://digg.com/submit”？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f10%2f22%2fThe-Birth-of-a-Semiconducting-Metal-Organic-Framework-By-Soxur-Coordination%2f&title=The+Birth+of+a+Semiconducting+Metal+Organic+Framework+By+Soxur+Coordination“><img class=“LightSocial”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/digg.png”alt=“digg this”title=“digg t他的“/>.<a><a 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social“a”href=“http://twitter.com/home？”status=reading+http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f10%2f22%2fthe-birth-of-a-semiconducting-metal-organic-framework-by-sulfur-coordination%2f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/twitter.png“alt=”post on twitter“title=”post on twitter“/><a class=”light social_a“href=”http://www.google.com/buzz/post？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f10%2f22%2fThe-Birth-of-a-Semiconducting-Metal-Organic-Framework-by-Sour-Coordination%2f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/google_buzz.png“alt=”google buzz（aka）。google reader）“title=”google buzz（aka.google reader）“/>.<a>.<div> //www.xcmww.com/cc/2018/10/22/the-birth-of-a-semiconducting-metal-organic-framework-by-sulfur-coordination/feed/ 0 //www.xcmww.com/cc/2018/10/04/hot-chemcomm-articles-for-九月三日/ //www.xcmww.com/cc/2018/10/04/hot-chemcomm-articles-for-september-3/回复 清华大学，2018年10月4日15:25:11+0000 丽贝卡威瑟斯 未分类 //www.xcmww.com/cc/？P＝9428 在2018年11月4日之前，以下所有裁判员推荐的条款都是免费的。柳州高，吡啶硼酰自由基催化N-羟基邻苯二甲酰亚胺酯脱羧烷基化，王国强，Jia Cao丹丹元，郑旭，郭学文、李淑华。公社，2018，预告文章doi:10.1039/c8cc06152a，UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU一种新的C，N-环金属化锇（II）芳烃抗癌支架[…] <p><strong>在2018年11月4日之前，以下所有裁判员推荐的文章都是免费的。<strong><p><a href=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06152a！DivAbstract“><strong>有机催化脱羧基烷基化of<em>n<-hydroxy邻苯二甲酰亚胺酯enabled by pyridine boryl arkets.<strong><a><br/>liuzhou gao，王国强，Jia Cao丹丹元，郑旭，郭学文，李淑华<br/><em>chem.社区->2018，advance article<br/><strong>doi:<strong>10.1039/c8cc06152a，Communication<p><p><a href=“//www.xcmww.com/cc/files/2018/10/1.jpg”><img class=“AlignCenter wp-image-9431”src=“//www.xcmww.com/cc/files/2018/10/1.jpg”alt=“”width=“337”height=“183”srcset=“//www.xcmww.com/cc/files/2018/10/1.jpg 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Wu王玮薛朝庄、吴涛<br/><em>chem.社区->2018年，<strong>54<strong>，11272-11275<br/><strong>doi:<strong>10.1039/c8cc0697b，Communication</p><p><a href="//www.xcmww.com/cc/files/2018/10/4.jpg"><img class="aligncenter size-full wp-image-9434" src="//www.xcmww.com/cc/files/2018/10/4.jpg" alt="" width="221" height="207" /></a></p><p style="text-align: center">_______________________________________________________________________________</p><p><a href="https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06281a！DivAbstract“><strong>Y形BolapolyPhiles的自组装中切向和共轴液晶蜂窝之间的过渡</strong><a><br/>Anne Lehmann，Marko Prehm常龙晨冯柳向冰增Goran Ungar和Carsten Tschierske<br/><em>Chem.社区->2018，advance article<br/><strong>doi:<strong>10.1039/c8cc06281a，Communication<p><p><a href=“//www.xcmww.com/cc/files/2018/10/5.jpg”><img class=“AlignCenter wp-image-9435”src=“//www.xcmww.com/cc/files/2018/10/5.jpg”alt=“”width=“309”height=“159”srcset=“//www.xcmww.com/cc/files/2018/10/5.jpg 399w，//www.xcmww.com/cc/files/2018/10/5-300x154.jpg 300w“尺寸=”（最大宽度：309px）100vw，309px" /></a></p><p style="text-align: center">_______________________________________________________________________________</p><p><a href="https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06966b#!divabstract“><strong>解开聚糖的异构异构异构性：离子迁移率分离in structures for lossless ion manipulations.<strong><a><br/>gabe nagy，艾萨克·K。阿塔，桑迪利亚诉B.Garimella柯琦堂耶希玛易卜拉欣，埃林S贝克和理查德D。史密斯<br/><em>chem.社区->2018，advance article<br/><strong>doi:<strong>10.1039/c8cc06966b，communication<p><a href=“//www.xcmww.com/cc/files/2018/10/6.jpg”><img class=“AlignCenter size full wp-image-9436”src=“//www.xcmww.com/cc/files/2018/10/6.jpg”alt=“”width=“317”height=“215”srcset=“//www.xcmww.com/cc/files/2018/10/6.jpg 317w，//www.xcmww.com/cc/files/2018/10/6-300x203.jpg 300w“尺寸=”（最大宽度：317px）100vw，317px“/>.<a><p><div class=“lightsocial_container”><a 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social_img”src=“//www.xcmww.com/cc/wp-content/plugins/light-social/google_buzz.png”alt=“google buzz（aka）。google reader）“title=”google buzz（aka.google reader）“/>.<a>.<div> //www.xcmww.com/cc/2018/10/04/hot-chemcomm-articles-for-september-3/feed/ 0 //www.xcmww.com/cc/2018/10/02/chemcomm-emerging-researcher-druceship-now-open-2/ //www.xcmww.com/cc/2018/10/02/chemcomm-emerging-researcher-dresship-now-open-2/回复 星期二，2018年10月2日15:37:00+0000 丽贝卡威瑟斯 未分类 //www.xcmww.com/cc/？P＝9425 认识一个值得承认的杰出的新兴科学家吗？现提名2019年化学委员会新兴研究者讲师 <p><span style=“color:black；font-family:'arial'，sans-serif；font-size:9pt”>我们很高兴欢迎2019年新兴调查员讲师提名<em><span style=“font-family:'arial'，sans-serif“>chemcomm.</span><em><span><p><span style=“color:black；font-family:'arial'，sans-serif；font-size:9pt”>所有提名必须是收信人<strong><span style=“font-family:'Arial'，sans-serif“>2019年1月25日星期五<span><strong><span><p><p><em><b><span style=“color:014682；font-family:'Arial'，sans-serif；font-size:9pt”>chemcomm<b><em><strong><span style=“color:014682；font-family:'Arial'，sans-serif；font-size:9pt“>Emerging Investor Teacheship<span><strong><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt”><br/><a href=“//www.xcmww.com/cc/files/2017/11/cc.jpg”><img class=“wp-image-8747 AlignRight”src=“//www.xcmww.com/cc/files/2017/11/cc-300x300.jpg”alt=“”width=“175”height=“175”srcsset=“//www.xcmww.com/cc/files/2017/11/cc-300x300.jpg 300w，//www.xcmww.com/cc/files/2017/11/cc-150x150.jpg 150w，网址：//www.xcmww.com/cc/files/2017/11/cc.jpg 396w“尺寸=”（最大宽度：175px）100vw，175px“/></a>•承认处于独立学术生涯早期阶段的新兴科学家。<br/>合格的被提名者应该在2010年9月15日或之后完成他们的博士学位。<span><p><strong><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>讲师职位详细信息r:black；font-family:'arial'，sans-serif；font-size:9pt“><br/>将邀请讲师的接受者在12个月内在三个不同的地点进行演讲，其中至少有一个活动在国际会议上进行。<br/>接受方将收到1500英镑的捐款，用于支付其讲座的旅费和住宿费，以及证书。<br/>收件人将被要求为日记提供一篇评论文章。<span><p><strong><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>how to design.<span><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt”><br/>self-nomination is not permitted.提名者必须将以下内容发送给编辑团队<em><span style=“font-family:'Arial'，sans-serif“>via</span><em><strong><span style=“font-family:'Arial'，sans-serif”><span><strong><span><a href=“mailto:chemcomm rsc@rsc.org”><b><span style=“color:014682；font-family:'Arial'，sans-serif；text-decoration:none”>chemcomm rsc@rsc.orgpan><b><a><span style=“color:black；font-family:'arial'，sans-serif；font-size:9pt“>by<strong><span style=“font-family:'arial'，sans-serif”>Friday 25th January 2019</span><strong><br/>Recommendation Letter，包括名字，提名人的联系方式和网址。<br/>提名人的一页简历，包括他们的教育总结，关键职业成就的日期，一份由五家顶级独立出版物组成的清单，出版物和专利总数，以及其他自尊指标，连同职业独立性的证据。<br/>候选人迄今为止最好的出版物的副本（由提名人判断）。<br/>两份独立推荐人的推荐信。这些人不应该是来自同一机构的人，也不应该是候选人的博士后或博士生导师。<span><p><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>提名人和独立推荐人应该对候选人的演讲技巧发表评论。<span><p><span style=“color:black；font-family:'Arial'，sans-serif；字体大小：9pt“>不完整的提名或不符合上述要求的提名将不予考虑，对于任何丢失或不正确的文档，将不会联系被提名者。<span><p><strong><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>选择过程</span><strong><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt”><br/>The edition team will screen each nomination for eli根据所提供的提名文件，列出候选人的候选名单。<br/>候选人将被要求提供一份简要的支持声明，概述其主要成就，强调他们工作的影响，并证明他们为什么值得参加特定的演讲。<br/>然后，由The<em>Chemcomm编辑委员会成员组成的选择小组将选出并认可演讲的接受者。获胜者将在2019年上半年宣布。<span><p><em><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>nb:please note that members of the selection panel from the.<span><em><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>chemcomm<em><span style=“font-family:'Arial'，sans-ser如果“>编委会没有资格提名，或提供参考资料，对于本次讲座，请参见。<span><em><span><p><span style=“color:black；font-family:'Arial'，sans-serif；font-size:9pt“>for any queries，在＜/SPAN＝“Melto：CycMCMRSC@ RSC.org”＞SPAN风格=“颜色：014682：字体家族：ArAy”，SANS serif；文本修饰：没有“> CSCCOM 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//www.xcmww.com/cc/2018/09/24/阴离子如何对抗室内有机污染物/响应 周一，2018年9月24日11:35:05+0000 刘天宇 热门文章 物理的 原位 室内空气污染物 机制 负空气离子 //www.xcmww.com/cc/？P=9414 室内空气质量对公众健康至关重要。长期暴露于室内有机污染物（IOCS）中，包括醛和苯同系物，大大增加患呼吸道疾病的风险。近年来，负空气离子（NAIS）是一种很有前途的降解IOC的材料。NAI是通过电离空气产生的带负电荷的离子。然而，有限公司 <p>室内空气质量对公众健康至关重要。长期暴露于室内有机污染物（IOCS）中，包括醛和苯同系物，大大增加患呼吸道疾病的风险。近年来，负空气离子（NAIS）是一种很有前途的降解IOC的材料。NAI是通过电离空气产生的负电荷离子。然而，对分解反应机理的有限理解阻碍了NAI清洗的安全性评估和广泛采用。<p>a group of chinese researchers led by jin ming lin of thinghua university recently exhibited in<em>chemcomm<em>a powerful tool to explaves the reaction mechanisms.他们建立了一个与NAI发电机集成的系统，IOC喷雾器和质谱仪（图1）。主要含有CO的NAIS由空气电离产生。然后，这些阴离子混合并与喷雾器反应，将IOC送至质谱仪入口前。反应过程中产生的所有物种均通过惰性n<sub>2<sub>for characterization直接带入质谱仪。<p><div id=“attachment_”style=“width:390px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2018/09/1-1.jpg”><img class=“wp-image-9415”src=“//www.xcmww.com/cc/files/2018/09/1-1.jpg“alt=”width=“380”height=“278”srcset=“//www.xcmww.com/cc/files/2018/09/1-1.jpg 781W，//www.xcmww.com/cc/files/2018/09/1-1-300x220.jpg 300w，//www.xcmww.com/cc/files/2018/09/1-1-768x562.jpg 768w“尺寸=”（最大宽度：380px）100vw，380px“/><a><p class=“wp caption text”><em><strong>Figure 1</strong>。集成系统的实验设置。.<em><p><div><p>This device explawed real-time reaction dynamics by identifying the reaction intermediates.一个共同的国际奥委会的质谱，甲醛，当与CO反应时，如图2a所示。将质量电荷比（m/z）为45.10和60.10的两个显著峰分配给hcoo^–and co<sub>3<sub>^–，分别。此外，仅当存在甲醛时才检测到45.10峰（图2b）。根据这些观察结果，作者得出结论认为，CO<sub>3导致甲醛降解的主要途径是CO<sub>3<sub>sup>––––––––––––––––––––––––––––––––––––––––使用相同的仪器，作者还提出了CO<sub>3<sub>^–和苯同系物或酯类之间的反应如何进行。<p><div id=“attachment_”style=“width:1222px”class=“wp caption aligncenter”><a href=“//www.xcmww.com/cc/files/2018/09/2_n.jpg”><img class=“wp-image-9418 size full”src=“//www.xcmww.com/cc/files/2018/09/2_n。jpg“alt=”width=“1212”height=“357”srcset=“//www.xcmww.com/cc/files/2018/09/2_n.jpg 1212W，//www.xcmww.com/cc/files/2018/09/2_n-300x88.jpg 300w，网址：//www.xcmww.com/cc/files/2018/09/2_n-768x226.jpg 768W，网址：//www.xcmww.com/cc/files/2018/09/2_n-1024x302.jpg 1024w“尺寸=”（最大宽度：1212px）100vw，1212px“/><a><p class=“wp caption text”><strong>Figure 2<strong>。（a）CO<sub>3<sub>^–和10 ppm甲醛之间反应中间体的质谱。（b）m/z=60.10和45.10峰的峰值强度随运行时间的变化。甲醛在7.0-14.0 min.期间存在。<p><div><p>The results obtained by this study can greately deep the understance of nai based chemistry.新利手机客户端研究涉及带电反应物的大范围其他化学反应的动力学也很有用。<p><p><p><strong><u>to find out more please read:<u><strong><p><strong><a href=“https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc05795h”！divabstract“target=”ou blank“rel=”noopener“>通过质谱法实时表征负空气离子诱导的室内有机污染物分解于莉Mashooq Khan孙嘉树和李金明公社。.<em>.<strong>，2018，doi:10.1039/c8cc05795h</p><p><p><strong><u>about the blogger:<u><strong><p><img class=“AlignLeft”src=“http://liutianyuresearch.weebly.com/uploads/9/1/0/7/91072250/liu-tianyu-photo.jpg？187“alt=”width=“112”height=“134”/>刘天宇获得博士学位。（2017）加州大学新利手机客户端化学专业，美国的圣克鲁斯。他热衷于科学传播，向公众和具有不同研究专长的科学家介绍尖端研究。他是化学的博客作家。common.<em>和<em>chem.科学>杂志。有关他的更多信息，请访问http://liutianyuresearch.weebly.com/“>http://liutianyuresearch.weebly.com/<a><p><div class=“lightsocial\u container”><a class=“lightsocial\u a”href=“http://digg.com/submit”？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f09%2f24%2fhow do阴离子与室内有机污染物作斗争%2f&title=how+do+阴离子+斗争+室内+有机+污染物%3f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/digg.png“alt=”digg this“title=”digg“/><a class=”light social“a”href=“http://www.reddit.com/submit？url=http%3a%2f%2fwww.xcmww.com%2fcc%2f2018%2f09%2f24%2fhow do阴离子与室内有机污染物作斗争%2f&title=how+do+阴离子+斗争+室内+有机+污染物%3f“><img class=“light social”img“src=”//www.xcmww.com/cc/wp-content/plugins/light-social/reddit.png“alt=”reddit this“title=”reddit this“/><a class=”light 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